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3-ureidopropionic acid n-carbamoyl-beta-alanine alanine uracil urea beta pyrimidine butyldimethylsilyl tert propanoic carbamoyl phosphate compound phenyl graphical 3d rendering chemistry chemical bioactive cell biochemistry molecule molecular structural structure formula skeletal geometry ball stick metabolite metabolism biosynthesis cycle mechanism pathway path catabolism biosynthetic hmdb intermediate biogenesis substrate precursor synthesis derivative bioprecursor