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cucurbalsaminol cucurbitane triterpenoid balsam apple momordica balsamina cucurbitacin rendering anti-aging alternative medicine biosynthesis flavonoid natural herb precursor herbalism cycle biogenesis prescription drug parasympathomimetic food additive intermediate phytochemical mechanism plant metabolism nutrient healthy aging substrate dietary enzyme antioxidant contractor metabolite nutraceutica endogenous derivative synthesis pharmacopoeia pathway pharmacognosy biosynthetic vitamin alkaloid phytotherapy catabolism herbal