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Sion City Capital Of The Canton Of Valais. Sion - A City In Southwestern Switzerland, In The Rhone Valley. Sion Is The Capital Of The Canton Of Valais. In A City That Includes Museums, Remains Of Ramparts And Castle Ruins Of The Thirteenth Century, The Cathedral Of The Fifteenth Century, Town Houses From The Sixteenth To The Eighteenth Century, And The Town Hall Of The Seventeenth Century